Heisenberg

My first query is why does he claim the position and period of an electron to be unobservable “in principle”? There was theoretically no reason (at THAT time) to doubt that these quantities could be measured, though certainly they were indeterminate practically.

Werner Heisenberg obviously disagreed with this assumption of yours and it just happened that his ability to disagree made him a founder of quantum mechanics.

He has spent several years by trying to develop “quantized planetary” models of the helium atom etc. before he understood that this failing project is failing for fundamental reasons. Such a helium with well-defined positions would be described by a chaotic 3-body problem and there would be no way how it could be consistent with the known regular behavior of the helium atom (and other atoms and other coherent systems), including the sharp spectral lines.

So Heisenberg was able to see in 1925 something that you can’t see now: that the electrons can’t be going along any particular trajectories while they’re in the atoms. Instead, what is observed is that they have a totally sharp energy from a possible list, the spectrum – something we can really observe via the photons that atoms emit or absorb. To conclude that electrons can’t be going along particular classical trajectories in the atoms, he didn’t have to wait for measuring apparatuses that would be sufficiently accurate. He was able to make this conclusion out of the available data by “pure thought”, and he was right.

— Lubos Motl

2014.10.04 Saturday ACHK