The second law of thermodynamics’ derivation (Ludwig Boltzmann’s H-theorem) is with respect to an observer.

How does an observer keep losing microscopic information about a system?

— Me@2017-02-12 07:37:54 PM

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This drew the objection from Loschmidt that it should not be possible to deduce an irreversible process from time-symmetric dynamics and a time-symmetric formalism: something must be wrong (Loschmidt’s paradox).

The resolution (1895) of this paradox is that the velocities of two particles *after a collision* are no longer truly uncorrelated. By asserting that it was acceptable to ignore these correlations in the population at times after the initial time, Boltzmann had introduced an element of time asymmetry through the formalism of his calculation.

— Wikipedia on *Molecular chaos*

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Physical entropy’s value is with respect to an observer.

— Me@2017-02-12 07:37:54 PM

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This “paradox” can be explained by carefully considering the definition of entropy. In particular, as concisely explained by Edwin Thompson Jaynes, definitions of entropy are arbitrary.

As a central example in Jaynes’ paper points out, one can develop a theory that treats two gases as similar even if those gases may in reality be distinguished through sufficiently detailed measurement. As long as we do not perform these detailed measurements, the theory will have no internal inconsistencies. (In other words, it does not matter that we call gases A and B by the same name if we have not yet discovered that they are distinct.) If our theory calls gases A and B the same, then entropy does not change when we mix them. If our theory calls gases A and B different, then entropy *does* increase when they are mixed. This insight suggests that the ideas of “thermodynamic state” and of “entropy” are somewhat subjective.

— Wikipedia on *The mixing paradox*

— Wikipedia on *Gibbs paradox*

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2021.08.07 Saturday (c) All rights reserved by ACHK

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